We use cookies to help provide and enhance our service and tailor content and ads. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. These metrics are regularly updated to reflect usage leading up to the last few days. Thermal Elimination of Precursors to Poly(phenylenevinylene) with a Macrocounterion versus a Small Counterion: A Coordinated Experimental and Simulation Study. For permission to reproduce, republish and D. Michael Byler, Yogesh Patel, Georgia A. Arbuckle-Keil. This may take some time to load. Go to our Find more information about Crossref citation counts. Shangli Wang, Wei Zhao, Xiaoqian Xu, Si Cheng, Lijuan Fan. These result in a new double bond, such as in Ei elimination. Thermodegradation kinetics of a hybrid inorganic–organic epoxy system. Correlation between Annealing-Induced Growth of Nanocrystals and the Performance of Polymer: Nanocrystals Hybrid Solar Cells. These reactivities parallel the π-bond order of the CN bond, though the exceptional reactivity of 2-ethoxythiazole is attributed to additional acceleration through +M electron release from sulphur to nitrogen. Arvind Sreeram, Nimitt G. Patel, Ramaswamy I. Venkatanarayanan, Stephan J. DeLuca, Philip A. Yuya, Sitaraman Krishnan. Article Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. Find more information about Crossref citation counts. James N. Wilking, Bing Hsieh, Georgia A. Arbuckle-Keil. In papers with more than one author, the asterisk indicates the name of the author to whom inquiries about the paper should be addressed. The elimination reaction consists of three fundamental events, and they are; Proton removal. Decomposition behavior of epoxy-resin systems cured by diamines. Andrew C. Grimsdale, Khai Leok Chan, Rainer E. Martin, Pawel G. Jokisz and Andrew B. Holmes . Mechanism of Formation of Aromatic Vinylphosphonium Salts via the Peterson Olefination. Sulfonium precursor routes are the most popular synthetic routes to light-emitting poly(p-phenylene vinylene) (PPV) thin films. The elimination reaction remains less understood. F. Massuyeau,, H. Aarab,, L. Mihut,, S. Lefrant,, E. Faulques, and, J. Wéry, , E. Mulazzi and. E-mail: [email protected]. The relationship between addition reactions and elimination reactions is … If you are the author of this article you still need to obtain permission to reproduce To whom correspondence should be addressed. It is named for its discoverer, the Russian chemist Lev Aleksandrovich Chugaev (1873-1922), who first reported the reaction sequence in 1899. Information. An elimination reaction is a reaction in which two or more atoms, one of which is usually hydrogen, are removed from adjacent atoms in the reactant, resulting in the formation of a multiple bond. This reaction sequence was used to prepare an unsaturated [3.2.2] bridged bicyclic amide, which was The intermediate β-hydroxy silane may be isolated, and the elimination step - the Peterson Elimination - can be performed later. The Chugaev elimination is the pyrolysis of a xanthate ester, resulting in an olefin. At about 200 °C, the alkene is formed by an intramolecular elimination. Theoretical prediction of linear free energy relationships using proton nucleomers. Please reconnect. Arvind Sreeram, Nimitt G. Patel, Ramaswamy I. Venkatanarayanan, John B. McLaughlin, Stephan J. DeLuca, Philip A. Yuya, Sitaraman Krishnan. Color Tuning of Core–Shell Fluorescent Microspheres by Controlling the Conjugation of Poly(p-phenylenevinylene) Backbone. Find more information on the Altmetric Attention Score and how the score is calculated. Weili Yu, Hao Zhang, Hongru Tian, Haotong Wei, Wenxu Liu, Jian Zhu, Junhu Zhang, and Bai Yang . Finally, the pyrolysis of xanthate and acetate esters proceed through an "internal" elimination mechanism, the E i mechanism. You have to login with your ACS ID befor you can login with your Mendeley account.

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